Sublimation

A direct transition from a solid phase to a gaseous phase. Heated interplanetary dust or a comet can lose material through this process, changing its size and radiation-pressure coefficient or destroying it before gravitational or drag-driven evolution is complete.

For a locally linear ice temperature with positive gradient $G$ into the solid, a corrugated sublimation front receives a perturbation in heat flux proportional to its horizontal wavenumber $\alpha$. The Gibbs-Thomson effect suppresses short waves, giving the displayed quasi-static growth rate. It requires $V/(\kappa \alpha )\ll 1$ and $|\sigma |/(\kappa {\alpha }^2)\ll 1$, as well as a perturbation depth short enough for the linear background approximation. Unstable modes have $0<\alpha <\sqrt{G/\Gamma }$.

For a sublimating surface with exponentially absorbed volumetric heating, use a frame moving into the solid at speed $V$. Its steady heat equation is $k{T}^{\prime \prime }+\rho c_{p}V{T}^{\prime }+q_0{e}^{-\lambda z}=0$. The surface Stefan condition is $k{T}^{\prime }(0)=\rho LV$. Integrating over the half-space gives the displayed energy-limited speed. The surface gradient is positive, but the far field is colder, so the temperature has a subsurface maximum where melting can begin.

An irradiated grain loses solid material by sublimation. Its lifetime depends strongly on temperature and composition. In a planetary dust tail, a short lifetime can truncate the distribution well before a relative orbital wrap.

A spherical black grain of radius $a$ absorbs luminosity $L$ through projected area $\pi a^2$ and emits over $4\pi a^2$. Radiative balance at sublimation temperature gives $r_{\mathrm{sub}}=[L/(16\pi {\sigma }_{\mathrm{SB}}{T}_{\mathrm{sub}}^4){]}^{1/2}$. Grain size cancels only under the stated unit-efficiency approximation; shielding and wavelength-dependent emissivity change the result.

At fixed irradiation, heating per grain is independent of temperature while cooling is proportional to $T^4$. With positive heat capacity and intact grains, a positive temperature perturbation increases net cooling, and a negative one increases net heating. Fixed dust properties and sufficient dust-gas thermal coupling are necessary assumptions.

A thermal-stability argument that holds dust properties fixed can fail near a sublimation front. A rise in temperature can destroy grains, changing the absorption and emission efficiencies, the dust mass and the optical depth through which radiation reaches neighboring material. The heating and cooling laws then change along with the temperature.

Write the net heating schematically as $Q(T,a,{\rho }_d)$, where $a$ is grain size and ${\rho }_d$ is dust density. The response along an evolving state includes $Q_{a}da/dT$ and $Q_{{\rho }_d}d{\rho }_d/dT$, not only the fixed-grain derivative $Q_T$. These additional terms can reinforce or oppose the perturbation. The sign depends on geometry, radiation spectrum and dust–gas coupling, so the fixed-property result in thermal stability of externally heated blackbody dust does not by itself establish the stability of a sublimation front.