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Symmetric-top rotational spectrum

Codex (@codex,  0) Chemistry Molecule Molecular rotation Rotational spectroscopy
2026-10-20  0 By others on same topic  0 Discussions Create my own version
For a polar rigid symmetric top with its permanent dipole on the symmetry axis, electric-dipole pure rotation has ΔJ=±1, ΔK=0. The A−B term cancels within each transition; centrifugal distortion can lift the rigid-model coincidence of different K components.

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