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An Archimedean solid is a convex uniform polyhedron, excluding the Platonic solids and the infinite families of uniform prisms and antiprisms. Here uniform means that every face is a regular polygon and that the symmetry group acts transitively on the vertices of a polyhedron: a symmetry of the entire solid carries any chosen vertex of a polyhedron to any other. Merely having equal numbers of faces of each type at every vertex of a polyhedron is a weaker local condition.^[ref]

There are thirteen types under this convention, counting a mirror-image pair as one type. The infinite prism and antiprism families are excluded by convention even though their uniform members satisfy the same regular-face and global vertex-equivalence conditions.^[ref]

For example, the truncated octahedron has six square faces and eight regular hexagon faces. Counting face-edge incidences gives $(6\cdot 4+8\cdot 6)/2=36$ edge of a polyhedron; Euler characteristic then gives $36-14+2=24$ vertices of a polyhedron. At each vertex of a polyhedron, one square and two regular hexagons meet. The icosidodecahedron, with twenty equilateral triangles and twelve regular pentagons, gives a different regular-face combination.

A faceted, approximately equiaxed crystal is indicated. A truncated octahedron bounded by low-energy $\{111\}$ and $\{100\}$ facets is a plausible three-dimensional shape for an fcc metal particle; the hexagonal section alone does not uniquely distinguish it from other faceted polyhedra.

The Wulff construction minimizes ${\sum }_i{\gamma }_i{A}_i$ at fixed particle volume. Place a plane with normal ${\hat{\mathbf{n}}}_i$ a distance $h_i=C{\gamma }_i$ from a common centre and take the inner envelope. Low-surface-energy orientations survive as large facets. Annealing permits diffusion toward this equilibrium morphology, provided the time is sufficient. For a supported or strained alloy, substrate adhesion and elastic energy modify this simple free-particle construction.

Three suitable examples are cubes bounded mainly by $\{100\}$ facets, octahedra bounded by $\{111\}$ facets, and truncated octahedra bounded by both $\{111\}$ and $\{100\}$ facets. These are crystallographically distinct shapes rather than three arbitrary rounded particle outlines.

At fixed volume the thermodynamic equilibrium shape minimizes $G_{\mathrm{surf}}={\sum }_i{\gamma }_i{A}_i$, with an edge/corner correction when particles are very small. In the Wulff construction, facet support-plane distances scale as their interfacial free energies. Silver's clean low-index energies, selective adsorption of ligands or ions, solvent chemical potential and possible support contact alter those energies. Crystal twinning and elastic strain can add further costs or stabilize multiply twinned forms. A face with slow attachment kinetics can also survive during growth even when that morphology is not the thermodynamic equilibrium Wulff shape. Homogeneous nucleation describes where nuclei form; it does not guarantee an thermodynamic equilibrium final shape.