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A combustible substance can sustain a sufficiently rapid, heat-producing chemical reaction with a suitable oxidizing agent. In ordinary air this usually means combination with molecular oxygen, producing enough heat to maintain the reaction after ignition. A visible flame is not essential: carbon can glow as it undergoes combustion.

Combustibility depends on the surroundings and experimental conditions. A cold block of wax does not ignite merely because it meets air: heating must first provide combustible vapour and overcome the kinetic barrier to reaction. Finely divided iron burns much more readily than a massive bar because more surface is exposed per unit mass. Nor is oxygen universally required: molecular hydrogen can undergo combustion in chlorine. The expression “supports combustion” identifies the surrounding reactant in a particular experiment; it does not establish an absolute division between two kinds of chemical substance.

The wick supplies liquid wax by capillary action; wax vapour reacts with atmospheric oxygen, releasing the heat that keeps the supply going. The wick is a delivery system, rather than the principal fuel.

First, an external flame warms the wick and adjacent wax. Melting produces a small liquid reservoir, and capillary action draws it into the spaces between the wick fibres. Near the hot tip, evaporation and some pyrolysis supply gaseous fuel. Melting and evaporation are physical changes; pyrolysis and combustion change the chemical substances present. Once established, the candle flame transfers enough heat back to the wax to maintain this sequence.^[ref]

The candle flame is a diffusion flame. Its relatively dark inner region contains newly supplied fuel with limited access to oxygen. In the yellow luminous region, incomplete conversion of the hydrocarbons produces small soot particles, which become incandescent. Farther out, mixing supplies enough oxygen to consume most of the remaining fuel, carbon monoxide and soot. Thus the yellow light is largely thermal emission from hot particles, rather than a yellow gas.^[ref]

For a representative alkane component of paraffin wax, complete combustion has the chemical equationReal candle materials are mixtures, and some, such as fatty materials, already contain oxygen; the displayed chemical equation is an illustrative wax model. The principal products of complete combustion are carbon dioxide and water vapour. Convection carries the hot gases upward and brings fresh air into the flame. A cold collector can reveal condensed water; collecting the gases and passing them into limewater gives a calcium carbonate cloudiness from carbon dioxide.

Removing the oxygen supply, cooling the reaction zone, or cutting off wax delivery extinguishes the flame. The smoking wick immediately afterwards can still emit combustible vapour; without sufficient heat at the mixing zone, that vapour need not sustain a flame.

The porous fuel-delivery component of a candle. Capillary action transports molten wax through its fibres to the region supplying gaseous fuel.