Incoming links: Bohr-Sommerfeld model
Quantum numbers appear directly in the Schrödinger equation solution for the hydrogen atom.
However, it very cool that they are actually discovered before the Schrödinger equation, and are present in the Bohr model (principal quantum number) and the Bohr-Sommerfeld model (azimuthal quantum number and magnetic quantum number) of the atom. This must be because they observed direct effects of those numbers in some experiments. TODO which experiments.
E.g. The Quantum Story by Jim Baggott (2011) page 34 mentions:This refers to forbidden mechanism. TODO concrete example, ideally the first one to be noticed. How can you notice this if the energy depends only on the principal quantum number?
As the various lines in the spectrum were identified with different quantum jumps between different orbits, it was soon discovered that not all the possible jumps were appearing. Some lines were missing. For some reason certain jumps were forbidden. An elaborate scheme of ‘selection rules’ was established by Bohr and Sommerfeld to account for those jumps that were allowed and those that were forbidden.
Quantum Numbers, Atomic Orbitals, and Electron configurations by Professor Dave Explains (2015)
Source. He does not say the key words "Eigenvalues of the Schrödinger equation" (Which solve it), but the summary of results is good enough.- 1859-1900: see Section "Black-body radiation experiment". Continuously improving culminating in Planck's law black-body radiation and Planck's law
- 1905 photoelectric effect and the photon
- TODO experiments
- 1905 Einstein's photoelectric effect paper. Planck was intially thinking that light was continuous, but the atoms vibrated in a discrete way. Einstein's explanation of the photoelectric effect throws that out of the window, and considers the photon discrete.
- 1913 atomic spectra and the Bohr model
- 1885 Balmer series, an empirical formula describes some of the lines of the hydrogen emission spectrum
- 1888 Rydberg formula generalizes the Balmer series
- 1896 Pickering series makes it look like a star has some new kind of hydrogen that produces half-integer entries in the Pickering series
- 1911 Bohr visits J. J. Thomson in the University of Cambridge for his postdoc, but they don't get along well
- Bohr visits Rutherford at the University of Manchester and decides to transfer there. During this stay he becomes interested in problems of the electronic structure of the atom.Bohr was forced into a quantization postulate because spinning electrons must radiate energy and collapse, so he postulated that electrons must somehow magically stay in orbits without classically spinning.
- 1913 february: young physics professor Hans Hansen tells Bohr about the Balmer series. This is one of the final elements Bohr needed.
- 1913 Bohr model published predicts atomic spectral lines in terms of the Planck constant and other physical constant.
- explains the Pickering series as belonging to inoized helium that has a single electron. The half term in the spectral lines of this species come from the nucleus having twice the charge of hydrogen.
- 1913 March: during review before publication, Rutherford points out that instantaneous quantum jumps don't seem to play well with causality.
- 1916 Bohr-Sommerfeld model introduces angular momentum to explain why some lines are not observed, as they would violate the conservation of angular momentum.