Ciro Santilli @cirosantilli 34

In the case of the Schrödinger equation solution for the hydrogen atom, each orbital is one eigenvector of the solution.

Remember from time-independent Schrödinger equation that the final solution is just the weighted sum of the eigenvector decomposition of the initial state, analogously to solving partial differential equations with the Fourier series.

This is the table that you should have in mind to visualize them: en.wikipedia.org/w/index.php?title=Atomic_orbital&oldid=1022865014#Orbitals_table

Appears directly on Schrödinger equation! And in particular in the time-independent Schrödinger equation.

Show up in the solution of the quantum harmonic oscillator after separation of variables leading into the time-independent Schrödinger equation, much like solving partial differential equations with the Fourier series.

I.e.: they are both:

A linear map is a function $f:V_1(F)\to V_2(F)$ where $V_1(F)$ and $V_2(F)$ are two vector spaces over underlying fields $F$ such that:

A common case is $F=\mathbb{R}$, $V_1={\mathbb{R}}_m$ and $V_2={\mathbb{R}}_n$.

One thing that makes such functions particularly simple is that they can be fully specified by specifyin how they act on all possible combinations of input basis vectors: they are therefore specified by only a finite number of elements of $F$.

Every linear map in finite dimension can be represented by a matrix, the points of the domain being represented as vectors.

As such, when we say "linear map", we can think of a generalization of matrix multiplication that makes sense in infinite dimensional spaces like Hilbert spaces, since calling such infinite dimensional maps "matrices" is stretching it a bit, since we would need to specify infinitely many rows and columns.

The prototypical building block of infinite dimensional linear map is the derivative. In that case, the vectors being operated upon are functions, which cannot therefore be specified by a finite number of parameters, e.g.

For example, the left side of the time-independent Schrödinger equation is a linear map. And the time-independent Schrödinger equation can be seen as a eigenvalue problem.

In this solution of the Schrödinger equation, by the uncertainty principle, position is completely unknown (the particle could be anywhere in space), and momentum (and therefore, energy) is perfectly known.

The plane wave function appears for example in the solution of the Schrödinger equation for a free one dimensional particle. This makes sense, because when solving with the time-independent Schrödinger equation, we do separation of variable on fixed energy levels explicitly, and the plane wave solutions are exactly fixed energy level ones.

This equation is a subcase of Equation "Schrödinger equation for a one dimensional particle" with $V(x)=x^2$.

We get the time-independent Schrödinger equation by substituting this $V$ into Equation "time-independent Schrödinger equation for a one dimensional particle":

Now, there are two ways to go about this.

The first is the stupid "here's a guess" + "hey this family of solutions forms a complete basis"! This is exactly how we solved the problem at Section "Solving partial differential equations with the Fourier series", except that now the complete basis are the Hermite functions.

The second is the much celebrated ladder operator method.

The partial differential equation of non-relativistic quantum mechanics.

Experiments explained:

Experiments not explained: those that the Dirac equation explains like:

To get some intuition on the equation on the consequences of the equation, have a look at:

The easiest to understand case of the equation which you must have in mind initially that of the Schrödinger equation for a free one dimensional particle.

Then, with that in mind, the general form of the Schrödinger equation is:where:

The $\overrightarrow{x}$ argument of $\psi$ could be anything, e.g.:Note however that there is always a single magical $t$ time variable. This is needed in particular because there is a time partial derivative in the equation, so there must be a corresponding time variable in the function. This makes the equation explicitly non-relativistic.

The general Schrödinger equation can be broken up into a trivial time-dependent and a time-independent Schrödinger equation by separation of variables. So in practice, all we need to solve is the slightly simpler time-independent Schrödinger equation, and the full equation comes out as a result.

Existence and uniqueness: mathoverflow.net/questions/212913/existence-and-uniqueness-for-two-dimensional-time-dependent-schr%C3%B6dinger-equation

We select for the general Equation "Schrodinger equation":giving the full explicit partial differential equation:

The corresponding time-independent Schrödinger equation for this equation is:

Technique to solve partial differential equations

Naturally leads to the Fourier series, see: solving partial differential equations with the Fourier series, and to other analogous expansions:

One notable application is the solution of the Schrödinger equation via the time-independent Schrödinger equation.

Bibliography:

The time-independent Schrödinger equation is a variant of the Schrödinger equation defined as:

So we see that for any Schrödinger equation, which is fully defined by the Hamiltonian $\hat{H}$, there is a corresponding time-independent Schrödinger equation, which is also uniquely defined by the same Hamiltonian.

The cool thing about the Time-independent Schrödinger equation is that we can always reduce solving the full Schrödinger equation to solving this slightly simpler time-independent version, as described at: Section "Solving the Schrodinger equation with the time-independent Schrödinger equation".

Because this method is fully general, and it simplifies the initial time-dependent problem to a time independent one, it is the approach that we will always take when solving the Schrodinger equation, see e.g. quantum harmonic oscillator.