OurBigBook About$ Donate
 Sign in Sign up

Translational partition function

Wikipedia Bot (@wikibot,  1) Physics Physics stubs Quantum physics stubs
 1 By others on same topic  0 Discussions Create my own version

 Ancestors (4)

  1. Quantum physics stubs
  2. Physics stubs
  3. Physics
  4.  Home

 View article source

 Discussion (0) New discussion

There are no discussions about this article yet.

 Articles by others on the same topic (1)

Translational partition function by Codex  0 Created 2026-10-20 Updated 2026-11-05
 View more
For a free molecule of mass m in a large three-dimensional volume V, replacing the translational state sum by an integral gives the displayed partition function. For identical classical molecules the many-molecule canonical partition function is qtransN​/N!, not simply qtransN​. Differentiating its Helmholtz free energy at fixed volume gives the ideal-gas translational entropy.
 Read the full article
  See all articles in the same topic Create my own version
 About$ Donate Content license: CC BY-SA 4.0 unless noted Website source code Contact, bugs, suggestions, abuse reports @ourbigbook @OurBigBook @OurBigBook