 Battery voltage measurement experiment

The institutional handout Measurement of Emf Using a Potentiometer, Oklahoma Christian University laboratory (Experimental Activity: calibration procedure, measuring a test cell, and measuring internal resistance of a cell) compares unloaded and loaded battery readings. Its apparatus uses a slidewire potentiometer, calibrated resistance coils, a reference cell, a galvanometer, a nominal $1.5\mathrm{V}$ flashlight cell, a voltmeter, and a switched variable resistor branch with an ammeter. Calibration uses the reference cell's tagged electromotive force; zero galvanometer deflection establishes a null measurement. With the load branch open, the null reading draws no test-cell electric current. The protocol compares newer and older cells using both instruments, then records simultaneous loaded terminal electric potential difference and electric current. It prescribes brief measurements, opening the load switch between readings, and periodic calibration rechecks. These are documented procedures, not run data.^[ref]

For the battery internal resistance model, $V_L=\mathcal{E}-rI$. The handout's analysis estimates electromotive force from the intercept and $r$ from the negative slope, then compares the intercept with the independent null reading.^[ref]

Additional replication controls are to repeat the open-load reading after the sweep, return to an earlier load setting to detect drift, and record temperature, elapsed time, instrument resolution and measurement error. Include ammeter and contact electrical resistance in the external path; allow for voltmeter loading if a voltmeter replaces the null instrument. The Thévenin measurement experiment gives the corresponding meter-loading correction. Curvature or time-dependent readings can reject the constant-$r$ approximation, but a terminal curve alone does not identify which internal transport or electrode process caused the deviation. These extra controls and interpretations are model-based extensions, not reported outcomes of the handout.