 Manometer height-to-pressure calibration

The ideal measurement calibration is a straight line through the equal-pressure zero. For the stipulated water mass density and gravitational acceleration above, its slope is $9.81\mathrm{Pa}$ per vertical millimetre. A lower liquid mass density gives a larger length change for the same pressure, improving the height-reading contribution to measurement resolution but requiring more vertical space for a given pressure range. The pressure scale depends on the actual mass density, which depends on temperature; $1000\mathrm{kg}{\mathrm{m}}^{-3}$ here is a chosen model value, not an exact property of all water samples.

Suppose each liquid meniscus height is rounded to the nearest scale division $q=1\mathrm{mm}$. Each height measurement error lies within $q/2$, so the error in their difference lies within $q$. The resulting pressure error is bounded by $\rho gq=9.81\mathrm{Pa}$. To quantify a standard uncertainty, make the additional model assumption that the two rounding errors are independent random variables, each having a continuous uniform distribution on $[-q/2,q/2]$. Each then has variance $q^2/12$; adding the two variances givesHere $u$ denotes standard uncertainty. The $9.81\mathrm{Pa}$ worst-case bound and $4.0049\mathrm{Pa}$ standard uncertainty answer different questions. At $588.6\mathrm{Pa}$ they are respectively $1.67\%$ and $0.680\%$ of the reading. Shared reading bias or a different reading method can violate the assumed independence.

If the mass density, gravitational acceleration and height difference also have small independent standard uncertainties, a first-order estimate follows from the partial derivatives of $\Delta p=\rho g\Delta h$:This displays why a finer scale does not remove uncertainty in mass density or gravitational acceleration. A pressure transducer compared against the column needs its own differential-pressure calibration to establish an electrical response.