Negative melting-point slope of water
ID: negative-melting-point-slope-of-water
For a local illustrative ice–water melting calculation, stipulate , latent heat of fusion , solid mass density , and liquid mass density . These are explicitly stipulated rounded inputs, not measurements made here. The specific volume change on melting isThe common-pressure melting-point slope therefore givesA small increase in the common pressure thus lowers the melting temperature by about in this local model. Positive latent heat does not force a positive phase coexistence curve slope: ice contracts on conversion to liquid water. Increasing pressure favors the smaller specific volume. This calculation compares equilibrium states of the same two thermodynamic phases; extending its tangent to large pressures would require updated mass densities, latent heat of fusion, and the relevant ice phase diagram.
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