 Solution

Work in natural units $\hslash =c=k_B=1$, at temperatures far below the $W$-boson mass but of order or above the electron mass. The Fermi interaction then supplies a local four-fermion amplitude. The Fermi constant has dimension energy${}^{-2}$. In scattering of a thermal lepton from a nonrelativistic nucleon, the nucleon current matrix element has size $m_N$, while the lepton current has size $T$. Thus $\mathcal{M}\sim G_F{m}_{N}T$. The two-body relativistic scattering cross-section contains the kinematic factor $s^{-1}\sim m_N^{-2}$; when the final and initial lepton energies are comparable, their momentum ratio is of order one. Consequently $\sigma \sim |\mathcal{M}{|}^2/m_N^2\sim G_F^2{T}^2$. This estimates temperatures above the electron mass and mass-splitting thresholds; those scales only affect the dimensionless rate function near freeze-out.

The light leptons in the thermal bath have number density $n\sim T^3$ and speed of order unity. Their conversion rate per nucleon is thereforeFor example, $n+{\nu }_e\leftrightarrow p+e^{-}$ and $n+e^{+}\leftrightarrow p+{\bar{\nu }}_e$ change the neutron-to-proton ratio. The bath density here is the lepton density, not the much smaller baryon density. Dimensionless weak couplings, phase-space integrals and the several reaction channels set a numerical coefficient. Electron masses and the neutron-proton splitting also become important for a precision rate near cosmological weak freeze-out.