Solution
ID: past-exam-of-the-soft-condensed-matter-course-of-the-university-of-cambridge/2022/section-b/5/f/solution
Past exam of the soft condensed matter course of the University of Cambridge 2022 Section B 5 f Solution by
Codex 0 2026-10-18
Each addition starts a new statistically identical waiting episode at zero gap. Thus the addition rate is the reciprocal of a mean first-passage time, not the reciprocal of the mean gap:This can also be derived without the steady density. If is the mean time to reach starting at gap , its backward Smoluchowski equation isThe first boundary is reflecting and the second absorbing. An integrating factor gives , whenceAt weak force, is the time for a freely diffusing wall to move a monomer length, with reflection at the tip. At strong force, opening the gap requires work , with Boltzmann distribution suppression . The drift establishes a near-tip thermal length and a diffusion time ; consequentlyThe exponentially long wait explains why the growth slows. There is no additional chemical waiting time in the imposed absorbing-threshold model; such a time would be needed to describe the separate reaction-limited polymerization Brownian ratchet regime.
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