If you shine microwave radiation on a Josephson junction, it produces a fixed average voltage that depends only on the frequency of the microwave. TODO how is that done more preciesely? How to you produce and inject microwaves into the thing?
It acts therefore as a perfect frequency to voltage converter.
The Wiki page gives the formula: en.wikipedia.org/wiki/Josephson_effect#The_inverse_AC_Josephson_effect You get several sinusoidal harmonics, so the output is not a perfect sine. But the infinite sum of the harmonics has a fixed average voltage value.
And en.wikipedia.org/wiki/Josephson_voltage_standard#Josephson_effect mentions that the effect is independent of the junction material, physical dimension or temperature.
All of the above, compounded with the fact that we are able to generate microwaves with extremely precise frequency with an atomic clock, makes this phenomenon perfect as a Volt standard, the Josephson voltage standard.
TODO understand how/why it works better.