The magnetization is magnetic dipole moment per unit volume. In magnetostatics it produces
The magnetic field intensity obeys
so isolates free currents while accounts for bound currents. For a linear isotropic material, .
Ampere's law for a circular loop around the free line current gives
in both media. Therefore
At , the net bound surface-current density is
Hence its magnitude is
and for a positive current along it points along when , reversing when .
The electric polarization is electric dipole moment per unit volume. It produces
The electric displacement field is useful because
so it separates free charge from the bound charge represented by . In a linear isotropic dielectric, .
Spherical symmetry and Gauss's law for give, on both sides of the interface,
Thus
With pointing from medium one to medium two, the net bound sheet charge at is the polarization jump
If one assigns surface charge separately to the inner body and outer medium, their contributions are and ; their sum is the displayed physical interface charge.
A dielectric is an electrically insulating material whose bound positive and negative charges can be displaced slightly by an electric field, producing electric polarization without sustained conduction current. Its macroscopic electric response is described by its permittivity.
At coexistence, . Stability says
Thus crosses zero with negative slope as increases through . On the two smooth phase branches,
Therefore
The transition from phase II to phase I consequently absorbs positive latent heat .
A first-order phase transition occurs where two phases have equal Gibbs free energy but a first derivative of that free energy is discontinuous. Typical jumps occur in
A nonzero entropy jump gives a nonzero latent heat .
The fundamental thermodynamic relation is
Because is extensive, the Euler theorem for homogeneous functions gives
Substitution into the Gibbs free energy therefore yields
For a one-component equilibrium phase, the intensive chemical potential depends on the intensive state variables and .
The Carnot theorem states that no engine between two fixed heat reservoirs can be more efficient than a reversible engine, and that all reversible engines between those reservoirs have the same efficiency. Thus the heat ratio of a reversible engine depends only on the two reservoirs. Its multiplicative consistency for three reservoirs permits a state variable , unique up to an overall scale, such that
Fixing one reference value defines the thermodynamic temperature scale, and the reversible efficiency is
The radial factor
is sharply peaked, for large , near
Requiring the orbit to lie inside a disk of radius permits
Thus the total degeneracy at fixed is, up to the negligible boundary correction,
Since the disk has area , the degeneracy of a Landau level per unit area is
For either sign of the charge-field product, replace by .
The factor is an eigenstate of longitudinal momentum with . The integer is the azimuthal angular momentum quantum number, since has eigenvalue .
For
direct differentiation gives
Regularity and cancellation of the term require for . Cancellation of the terms requires
assuming . The remaining radial energy is independent of :
This is the lowest Landau level. If , the same family uses nonpositive angular-momentum quantum numbers and replaces .
With the magnetic minimal coupling convention for charge ,
Here , , and
Therefore in Cartesian coordinates
In cylindrical coordinates this is
This choice of is the symmetric gauge.
The required dipole matrix element is
where differentiating the elementary Laplace integral for evaluates the last integral. Hence
Put and . The continuum transition probability at long times uses
Since
the total escape probability becomes
For the attractive delta potential,
Substitution gives the requested leading-order result:
To first order in , time-dependent perturbation theory replaces the state on the right-hand side by its unperturbed value . The bound state is even, while the position operator is odd. The parity selection rule therefore gives
so and, with no initial continuum component,
Projection onto the odd state gives
Writing and integrating from zero to yields
Insert the stated expansion into the Time-dependent Schrödinger equation
When the derivative acts on each free phase, its energy factor is cancelled by the action of on the corresponding eigenstate. The remaining terms obey
Division by gives
There are two bifurcations in , both at .
Near , append . The plane is invariant and tangent to the extended center subspace, so it is an extended center manifold. The reduced equation is exactly
Its leading terms have two branches, and , which cross and exchange their center-direction stability. Hence this is a transcritical bifurcation.
For the bifurcation at , set
The extended system becomes
Solving the centre-manifold invariance equation for gives
Substitution into the equation yields
For this has two nearby equilibria , while for it has none. It is therefore a saddle-node bifurcation. These reductions are collected in bifurcations of the 2022 Cambridge quadratic-cubic system.

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