Argon-37 is a radioactive isotope with protons and neutrons. It undergoes electron capture to chlorine-37, with an approximately -day half-life:
The mass number is unchanged while the nuclear charge decreases by one. Atomic vacancies left by the captured electron can produce detectable low-energy radiation during atomic relaxation.
Argon-37 made from chlorine was the counted product in the radiochemical solar-neutrino experiment. The method separated rare radioactive argon atoms from a much larger chlorine target, connecting nuclear counting to a very weak astronomical signal.[ref]

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