An azeotrope has equal coexisting liquid and vapor compositions: . Ordinary fractional distillation cannot cross this composition boundary at fixed pressure; more packing does not remove it. A constant head temperature therefore does not establish a pure chemical substance.[ref]
Distillation introduction. Chem2O06 Laboratory Manual by McMaster University; Liquids that Form Azeotropes, constant-temperature mixtures and limits on separation
The stipulated model has throughout , so it has no interior azeotrope and cannot represent this limit. Articles by others on the same topic
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