Let the specimen rotate uniformly with angular velocity . In its rotating reference frame, the internal Hamiltonian contains
Here is the internal angular momentum operator about the rotation axis, and contains the internal interactions and any imposed magnetic field expressed in that frame. It does not include the separately treated rigid body's rotational kinetic energy. For a sector with magnetic moment , the rotational term has exactly the form of a magnetic dipole potential energy:
This Barnett equivalent magnetic field has tesla units, with the angular convention for the signed gyromagnetic ratio: is in radians per second, not revolutions per second. Its sign matters. For an electronic contribution with , positive favors positive and negative . A sector with has the opposite magnetic sign. Equal need not correspond to equal Barnett fields for sectors having different gyromagnetic ratios.
A short derivation fixes the sign independently of any material model. Put and transform a laboratory quantum state by . The Schrödinger equation gives
The transformed laboratory term is denoted by ; a laboratory perturbation not stationary in the rotating frame can make it time dependent. Establishing a steady thermal response also requires exchange of internal angular momentum with the rotating body, for example through spin-lattice relaxation. A mere relabeling of coordinates cannot polarize isolated, unrelaxed spins.
The Barnett field is a useful description of spin-rotation coupling, not a claim that empty laboratory space acquires a uniform magnetic flux density . In particular, inserting it into the Lorentz force on an unrelated test electric charge is unjustified. A nearby magnetometer detects the specimen's actual stray magnetic field and backgrounds, rather than directly detecting this internal Hamiltonian parameter.

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