A differential form on a Lie group is bi-invariant when it is invariant under both left and right translations.
An adjoint-invariant symmetric bilinear form on a Lie algebra makes the displayed tensor alternating. If is invariant under the full group Adjoint representation, its left-translated three-form is also right-invariant. On left-invariant fields, the exterior derivative is by the Jacobi identity. The Killing form supplies such a on every semisimple Lie group. An overall sign change in the lowered structure-constant convention negates the form but not its invariance or closedness.
On a connected Lie group, a left-invariant differential 1-form is closed exactly when it is bi-invariant. Connectedness is essential: on every left-invariant 1-form is closed because its Lie algebra is abelian, while reflection conjugation negates every nonzero one.

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