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If $E\to B$ is an oriented real plane bundle, then $\mathcal{L}Gr(E)=\mathbb{P}(E)$ is an oriented circle bundle. Its transition rotations have twice the angle of those of $E$, so

Any symplectic form on $S^2$ orients its tangent bundle. Choose a compatible complex structure and inner product; this reduces the structure group to $SO(2)$. Since every line in an oriented symplectic plane is Lagrangian,is an oriented circle bundle.

If a transition function of $T{S}^2$ rotates vectors through an angle $\alpha$, its action on unoriented lines rotates the coordinate $e^{2i\theta }$ through $2\alpha$. The Euler class of the Lagrangian-line bundle of an oriented plane bundle therefore givesBy the Poincaré-Hopf theorem,for the chosen orientation, up to changing both signs. Hence the Euler number of $\mathcal{L}Gr(T{S}^2)$ is $\pm 4$, which is nonzero. A smoothly trivial oriented circle bundle has zero Euler class, so $\mathcal{L}Gr(T{S}^2)\to S^2$ cannot be smoothly trivial for any choice of symplectic form.