Coherent preparation and incoherent mixing

Choose the qubit computational basis $|0⟩,|1⟩$, also called the $Z$ basis, and the Hadamard basis $|\pm ⟩=(|0⟩\pm |1⟩)/\sqrt{2}$, also called the $X$ basis. Compare a coherent preparation of $|+⟩$ with choosing $|0⟩$ or $|1⟩$ at random with equal probabilities and discarding that label:These are original ideal preparation models. Their $Z$-basis probabilities are both $(1/2,1/2)$, because their quantum state populations agree. Their $X$-basis probabilities are respectively $(1,0)$ and $(1/2,1/2)$. Indeed $⟨+|{\rho }_{+}|+⟩=1$, whereas $⟨+|I/2|+⟩=1/2$. The missing off-diagonal quantum coherence therefore changes a prediction that the common populations cannot determine.

For a relative quantum phase $\varphi$, the coherent family instead hasThe last formula follows by adding or subtracting the two probability amplitudes before taking the squared modulus. At $\varphi =\pi$, the state is $|-⟩$ and the $X$ outcomes switch to $(0,1)$, while the $Z$ outcomes remain $(1/2,1/2)$. In contrast, $-|+⟩$ changes both components by the same global phase and retains the $X$ outcomes $(1,0)$. In photon polarization, the identification $|0⟩=|H⟩$, $|1⟩=|V⟩$ makes $|+⟩$ and $|-⟩$ the two orthogonal diagonal linear polarizations; these labels describe measurement bases, not spatial axes for photon spin.

Even perfect statistics in one basis cannot certify a preparation. The above $Z$ data fit both density matrices. Conversely, distinct preparation histories can yield the same quantum state:The off-diagonal terms cancel in the right-hand ensemble. Every measurement on the qubit alone then has identical probabilities for those two histories. A retained classical label would allow conditioning on different members of the quantum state ensemble; it is extra information beyond the unlabelled density operator.