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A quantum dot confines electronic motion in all three directions. A semiconductor dot can be thin enough that only one transverse subband is occupied, with discrete lateral states controlled by gates. In a rectangular hard-wall model,A smooth circular lateral confinement is often better approximated by $m^{\ast }{\omega }_0^2{r}^2/2$, giving ${ϵ}_{n_x{n}_y}=\hslash {\omega }_0(n_x+n_y+1)$ above the transverse ground energy. Shell $q=n_x+n_y$ contains $q+1$ orbitals, twice that many electrons before interactions split the spin degeneracy. Hence closed-shell electron numbers are $2,6,12,20,\dots$. These are single-particle quantum numbers; an interacting dot's states are many-electron eigenstates, not simply one orbital occupied by a whole charged island.

A perpendicular magnetic field changes the harmonic spectrum to the Fock-Darwin spectrum. For an electron of charge $-e$, take ${\omega }_c=eB/m^{\ast }>0$ and $L_z=\ell \hslash$ in the usual symmetric gauge. ThenReversing the definition of the angular label changes the displayed sign of its orbital term, not the set of energies. The Zeeman term lifts spin degeneracy, while exchange can favor parallel-spin filling in partially filled shells. These effects are distinguished by how peaks evolve with field rather than by identifying every irregular peak spacing with one-particle confinement.

For electrostatics, let $C_{\Sigma }=C_s+C_d+C_g$ and $Q_g=C_s{V}_s+C_d{V}_d+C_g{V}_g+Q_0$, where $Q_0$ represents a fixed offset charge in the chosen convention. The constant interaction model givesThe charging energy is conventionally $E_C=e^2/(2C_{\Sigma })$, whereas adjacent charge-state potentials differ byThis addition energy separates a capacitive contribution from orbital spacing. Exchange, nonuniform screening and correlations are corrections to the constant interaction model; a change in dot shape or effective capacitance can also alter spacings.

Connect the island weakly to source and drain reservoirs through tunnel barriers. sequential tunnelling is suppressed in a charge-stable region when neither adding nor removing an electron is energetically accessible. Sweeping the gate brings a charge electrochemical potential through the reservoir Fermi level, giving a Coulomb-blockade conductance peak. The gate lever arm is ${\alpha }_g=C_g/C_{\Sigma }$, so $\Delta V_g=E_{\mathrm{add}}/(e{\alpha }_g)$ locally if the capacitances and level spectrum do not vary appreciably. At finite source-drain bias, alignment with either reservoir defines the boundaries of a Coulomb diamond. Its slopes constrain capacitance ratios, and lines parallel to its edges can reveal excited-state transport. The conversion from a diamond's bias height to an energy depends on bias convention; a full-height/half-height factor must not be assumed without declaring the circuit.

A clear charging spectrum requires $k_{B}T$ and tunnel broadening $\hslash \Gamma$ smaller than the relevant addition energy; resolving individual orbital levels additionally requires them smaller than the orbital spacing. Tunnel resistances large compared with $h/e^2$ suppress strong charge fluctuations in the usual weak-junction regime. Blockade is not an assertion of mathematically zero current: higher-order cotunnelling can remain, and strong coupling or low-temperature spin correlations can invalidate the sequential model. An experimental check therefore combines gate sweeps with bias spectroscopy, temperature dependence and barrier tuning to separate level structure from broadening or uncontrolled charge traps.

In a primary vertical-dot experiment, gate-controlled current oscillations were converted into addition energies using finite-bias diamond spectroscopy; varying magnetic field then followed shell and spin filling. Reproducing enhanced addition energies at electron numbers 2 and 6 in several devices strengthened the shell assignment. The electron temperature was independently estimated above the refrigerator base temperature, an essential distinction when judging spectral resolution. Field-dependent reordering also revealed exchange effects beyond a purely spin-degenerate orbital model.^[ref]

A larger source–drain bias opens an energy window between reservoir electrochemical potentials. When a charge-addition/removal transition enters that window, sequential tunnelling becomes allowed even away from a zero-bias degeneracy. The low-conductance regions in a gate/bias map are Coulomb diamonds.

For an illustrative symmetric device with reservoir potentials $\pm e{V}_{\mathrm{SD}}/2$, let $q=Q_{\mathrm{ext}}/e$ and $E_{\mathrm{ch}}=e^2/C$. In the charge-$N$ interval, the classical blockade domain isIt shrinks to zero at $q=N\pm 1/2$. Unequal capacitances change edge slopes and voltage division; the figure's symmetry is a chosen model, not a universal device property.

Quantum confinement adds discrete single-particle levels and spin structure. In a constant-interaction approximation, successive addition energies contain $e^2/C$ plus the relevant orbital spacing, so diamond sizes need not all match. Excited-state tunnelling can produce extra conductance lines. At stronger coupling, cotunnelling and charge fluctuations can give leakage beyond a simple sequential classical model. Thus temperature and coupling must be small enough to resolve the charging and level structure separately.

A gated quantum dot is an electron island confined in all spatial directions, weakly coupled by tunnel barriers to source and drain and tuned by a plunger gate. Small capacitance makes charge addition costly, while confinement resolves orbital levels. In the constant-interaction model,The charging contribution to successive addition potentials is $e^2/C_{\Sigma }$; the often used charging-energy scale $E_C=e^2/(2C_{\Sigma })$ differs by a factor of two. Orbital spacing and spin filling add further structure.

For weak coupling, $k_{B}T$ and lifetime broadening must be smaller than the relevant addition energies to see Coulomb blockade. Sequential tunnelling proceeds when an addition level is inside the source-drain bias window and the appropriate charge states are accessible. A gate sweep gives conductance peaks near charge degeneracies and low conductance between them. A bias-versus-gate map shows Coulomb diamonds, with excited-state lines when additional levels enter the window. Their slopes and sizes depend on source, drain and gate capacitances and the bias convention. Cotunnelling gives higher-order transport inside nominally blocked regions; stronger coupling and many-body effects can invalidate the simple sequential picture.

Coherent dot states as a qubit. A single-electron spin has basis $|0⟩=|\uparrow ⟩$, $|1⟩=|\downarrow ⟩$ in a magnetic field, split by $E_Z=|g^{\ast }|{\mu }_{B}B$. A qubit is a controllable coherent state $a|\uparrow ⟩+b|\downarrow ⟩$, not just a pair of classical current levels. Initialize through spin-selective loading or relaxation; resonant magnetic or spin-orbit-assisted electrical driving produces rotations. Adjacent occupied dots can couple through a gate-controlled exchange interaction. In the weak-tunnel symmetric Hubbard limit,Local spin rotations combined with a suitable exchange entangling operation provide universal control in the ideal spin-qubit proposal. Gate pulses must avoid unwanted orbital excitation and leakage, and complete coherent operations before dephasing destroys the information.^[ref]

For measurement, place the reservoir electrochemical potential between Zeeman levels so that only one spin state can tunnel out, or use Pauli spin blockade in a double dot. A nearby quantum point contact or single-electron transistor detects the resulting charge change. Such spin-to-charge conversion makes transport useful for reading a spin even when the stored information is not itself a net current.^[ref]

A double dot can alternatively encode a charge qubit in left/right occupation, with Hamiltonian $H=(\epsilon {\sigma }_z+2t_c{\sigma }_x)/2$. It allows electrical control and charge sensing, but couples strongly to charge noise. Spin qubits also suffer hyperfine, electrical and spin-orbit-related noise, as well as relaxation and readout errors. An observed Coulomb diamond alone establishes charging physics, not initialization, coherent control or a functioning qubit.

Transport by successive real charge-state changes across weak tunnel barriers. Charge electrochemical potentials must enter the source-drain bias window; outside it sequential transport is Coulomb blocked. Higher-order virtual cotunnelling is a distinct process.