Crystal field theory 2026-10-20
Crystal field theory models the effect of surrounding ligand charges or dipoles on metal atomic orbitals. Directional repulsion splits the levels. Unlike molecular orbital theory, the simplest model does not explicitly construct covalent metal–ligand bonds.
For positive , expand the common radical as
Substitution into the stated crystal field theory energies gives
The leading straight-line asymptotes retain the terms linear in and constant in . The terms show from which side the interacting levels approach them.