Cuprate superconductor

A cuprate superconductor is a copper-oxide material exhibiting superconductivity, with layered copper-oxygen units central to its crystal structure. Chemical composition and oxygen content must accompany a quoted superconducting transition temperature; the nominal recipe of a mixed-phase pellet is not the composition of its superconducting constituent. The formal hole count in a cuprate illustrates the distinction between composition and electronic interpretation.

For a chosen homogeneous composition ${\mathrm{La}}_{2-x}{\mathrm{Ba}}_x{\mathrm{CuO}}_{4-\delta }$, assign formal oxidation states $+3$ to lanthanum, $+2$ to barium and $-2$ to oxygen. If $v$ is the mean formal copper oxidation state, charge neutrality requiresThe excess formal positive charge per copper relative to $+2$ is therefore $p_{\mathrm{formal}}=x-2\delta$. For stipulated $x=0.12$ and $\delta =0.01$, it is $0.10$; at $\delta =0.06$, it is zero. These are bookkeeping examples, not measurements of mobile carriers. The symbol $x$ here belongs to this declared formula, not the original mixed-phase recipe. A whole-pellet elemental ratio cannot simply be assigned to each constituent phase.

Charge neutrality alone does not locate holes. The lecture reviews oxygen-related carrier evidence and charge-$2e$ pairing from the Josephson effect and fluxoid and flux quantization in a superconductor. Pair charge does not establish phonon-mediated BCS theory for cuprate superconductors.^[ref]