The diffusion weighting b-value quantifies the encoding applied by a magnetic field gradient waveform in a diffusion measurement. For a refocused experiment in one spatial direction, define
Here is the angular gyromagnetic ratio, in radians per second per tesla, and includes the sign reversal caused by the refocusing pulse. The echo time is , with for refocusing of stationary spins. Thus has units and has units . The squared encoding history matters even though its final value is zero.[ref]
For unrestricted, isotropic Gaussian diffusion with constant diffusion coefficient , the otherwise matched signal ratio is . Here uses the same pulse timing and detection conditions with the applied diffusion-encoding gradients removed. The diffusion weighting b-value describes the experiment's weighting; describes the assumed sample model.
For an original unit check, . With , the ideal attenuation is . Quoting a numerical without its units can therefore cause a millionfold scaling error.
The Stejskal-Tanner equation gives for its equal rectangular pulses. More general waveforms require their own integral. For direction-dependent diffusion, a scalar alone cannot specify the complete directional encoding and response; a tensor description is needed.

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