The only zeros of , modulo the reciprocal lattice, are the two Dirac valleys in graphene,
At these momenta . Thus the two Dirac mass coefficients, measured in energy units, are , with . For ,
The two Dirac cones have opposite orientation, encoded by . A scalar sublattice offset gives equal-sign Dirac masses; imaginary second-neighbour hopping at gives opposite-sign Dirac masses. Both mechanisms open valley gaps
An observed band gap alone therefore cannot establish a Chern insulator. In particular, the gapless nearest-neighbour model of graphene and its sublattice-mass deformation should not be confused with the topologically nontrivial Haldane model.
A band gap closes when all three components of vanish. Since only at the two valleys, the phase boundaries are exactly . Usually one valley becomes massless; at , , both do. The occupied-band Chern number is undefined at every such touching, even if a numerical momentum grid misses its location.
Figure 1.
Haldane phases meet where a valley gap closes
. Original model calculation with the stated lower-band Berry-connection convention and . Left: integer Chern numbers; black curves denote singular parameters, where no Chern number is assigned. Right: the two valley gaps along ; the vertical axis shows valley gaps, rather than an assumption about global band extrema. No experimental data are plotted. Source. Details.