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Consider the diagonal matrix $D=2I_2$ and a Jordan blockBoth have characteristic polynomial $(t-2{)}^2$, trace $4$, determinant $4$, and eigenvalue $2$ with algebraic multiplicity two. But $\ker (D-2I)$ is the whole plane, whereas $(J-2I)(a,b{)}^T=(b,0{)}^T$ vanishes only when $b=0$. Their eigenspaces have different dimensions, so eigenvectors under similarity rules out matrix similarity. There is an even shorter proof: $S^{-1}(2I)S=2I$ for every invertible matrix $S$.

The missing information is how the linear operator acts beyond its eigenvectors. Here $D-2I=0$, while $J-2I\ne 0$ but $(J-2I{)}^2=0$. Their minimal polynomials are respectively $t-2$ and $(t-2{)}^2$. Over a field where the characteristic polynomial splits, the full sizes of the Jordan blocks, encoded by the Jordan normal form, determine the matrix similarity class.