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Introduce a constant filament bending modulus $B$, which sets the mechanical force scale. The filament has intrinsic curvature of an elastic filament ${\kappa }_0(s)$, and its actual signed curvature in a small-slope Monge representation is $\kappa \simeq {\zeta }_{xx}$. To quadratic order one may identify material arc length $s$ with $x$ in ${\kappa }_0$, whileAt fixed positive extension force, the mechanical potential is bending energy minus $FL$. Replacing $L$ by $\mathcal{L}-(\mathcal{L}-L)$ leaves, up to a force-dependent constant,Its first variation isThe higher-order Euler-Lagrange equation is thereforeFor a Fourier transform relation, take a periodic bulk segment, or a long-filament bulk approximation with negligible endpoint contributions; these are necessary boundary conditions because the question specifies no filament end conditions. Using $f(x)=\int \hat{f}(q)e^{iqx}dq/(2\pi )$, every nonzero wavenumber obeysA zero displacement mode is an arbitrary translation. In a periodic representation a constant intrinsic-curvature mode contributes a constant bending cost but no bulk slope, so it does not contribute to the following deficit. The Parseval identity givesFor clarity about finite normalization, on a periodic interval of length $L$ define ${\kappa }_n=L^{-1}{\int }_0^L{\kappa }_0(x)e^{-i{q}_{n}x}dx$, $q_n=2\pi n/L$. Then the equivalent exact quadratic-order formula isThis is force-extension of an intrinsically curved filament, determined by its particular fixed shape rather than by a thermal orientation entropy.

For an ensemble with quenched intrinsic curvature, first minimize each realization and then average the last expression, replacing $|{\kappa }_n{|}^2$ by its ensemble mean. For stationary bulk disorder, let $S_{\kappa }(q)$ be the power spectrum, normalized so that its correlation is $⟨{\kappa }_0(x){\kappa }_0(x+r)⟩=\int S_{\kappa }(q)e^{iqr}dq/(2\pi )$. The measurable mean deficit per unit projected length isIf the curvature is smooth enough that the second spectral moment is finite, one can take the large-force limit under this integral, obtaining the smooth-curvature high-force extension lawFor a stationary ensemble the integral is $L⟨({\kappa }_{0,x}{)}^2⟩$. Equivalently, the bulk slope is ${\zeta }_x\simeq -(B/F){\kappa }_{0,x}$; a plot of the mean deficit against $F^{-2}$ measures the mean squared intrinsic-curvature gradient, if $B$ is known. The $F^{-2}$ law is a smooth-curvature bulk result, not a universal law for every random filament. For example, ideal white intrinsic-curvature disorder with $S_{\kappa }(q)=S_0$ has an infinite second spectral moment; retaining the full integral instead gives $⟨\mathcal{L}-L⟩/L=S_0\sqrt{B}/(8\sqrt{F})$ in that ideal continuum model.

Endpoint conditions also matter. If each end is moment-free and has no transverse applied force, the natural conditions from the variation areat each end. These can produce a free-end curvature boundary layer of width $\ell =\sqrt{B/F}$. For a constant intrinsic filament curvature $\kappa$, integration of the higher-order Euler-Lagrange equation with zero transverse force gives $B({\zeta }_x{)}_{xx}-F{\zeta }_x=0$ and henceThe last formula follows by integrating ${\sinh }^2[(x-L/2)/\ell ]$, and tends to ${\kappa }^2{\ell }^3/2\propto F^{-3/2}$, despite the vanishing bulk curvature gradient. Thus a finite free-ended measurement must include or suppress endpoint bending before interpreting a bulk $F^{-2}$ fit.

For the freely jointed chain, rigid links have independent orientations, so the restoring force is entropic. Let $T$ now denote absolute temperature, and $\beta =1/(k_{B}T)$ with Boltzmann constant $k_B$. In the usual three-dimensional chain, a segment at polar angle $\theta$ has force energy $-Fb\cos \theta$. Its angular canonical partition function and the full chain partition function areDifferentiating $\log Z_N$ with respect to $\beta F$ yields the exact mean projected displacementHere $\mathcal{L}$ is the Langevin function; this is force-extension of a three-dimensional freely jointed chain, in the fixed-force canonical ensemble. At high extension, $\coth \xi =1+2e^{-2\xi }+\cdots$, soThus the smooth quenched-curvature bulk deficit falls as $F^{-2}$, whereas the three-dimensional freely jointed chain deficit falls as $F^{-1}$ and depends explicitly on temperature. The distinction is mechanical straightening of a fixed intrinsic shape versus orientational entropy; thermal bending fluctuations of a stiff filament have not been included in the first calculation.

If the comparison chain is also restricted to two dimensions, it is a planar freely jointed chain rather than the three-dimensional model. In this case,The last identity follows directly by differentiating the integral defining $I_0$; $I_0$ and $I_1$ are Modified Bessel functions of the first kind. At large $\xi$ the angular weight is proportional to $e^{-\xi {\theta }^2/2}$, giving $⟨\cos \theta ⟩\simeq 1-⟨{\theta }^2⟩/2=1-1/(2\xi )$. Consequently $Nb-⟨L⟩\sim N{k}_{B}T/(2F)$: the same inverse-force exponent, with half the three-dimensional coefficient. Both versions assume inextensible links and forces below the regime where the links themselves stretch.