Galactic chemical evolution follows the production, transport, dilution, locking, and loss of chemical elements as stars form and die and gas enters or leaves a galaxy.
An alpha element is an element such as oxygen, neon or magnesium associated with nucleosynthesis involving helium nuclei and massive-star burning. Core-collapse supernovae promptly return substantial abundances of these elements. Their abundance relative to iron can distinguish a rapid enrichment history from one with substantial delayed Type Ia supernova enrichment.
Massive stars produce prompt enrichment through core-collapse supernovae, whereas a Type Ia supernova follows binary stellar evolution and contributes substantial iron after a distribution of delays. A stellar population formed rapidly before much delayed enrichment can have a larger alpha-element to iron ratio than a stellar population formed over a prolonged interval. Relative abundance also depends on the initial mass function, stellar yields, and gas exchange; this is a chemical clock with model assumptions.
With well-mixed gas-phase metallicity , zero mass return, star formation rate , pristine galactic gas inflow , and constant stellar yield , mass conservation and metal accounting give and . Thus, for ,
The initial gas-phase metallicity gives the usual pristine-infall expression. Neglecting returned bulk mass while retaining a nonzero metal yield is a trace-metal idealization.
For and initially pristine gas, and the formed stellar mass is . If a fixed initial mass function supplies surviving tracers per unit formed mass, then and until the current gas abundance. Complete exhaustion gives a uniform normalized metallicity distribution function on . This is uniform in linear metallicity, not in its logarithm.
The gas fraction of a galaxy is commonly , using the gas and stellar masses remaining in the system. In a leaky-box model of galactic chemical evolution, it differs from the fraction of the initial gas reservoir. For an initially star-free box with outflow rate , . These different fractions give different-looking metallicity formulae and effective yields.
Galactic metallicity measures the abundance of elements heavier than helium in a galaxy. Gas and stars retain different time-weighted records of enrichment.
Gas-phase metallicity is the heavy-element abundance of interstellar gas. In star-forming galaxies it is commonly inferred from nebular emission lines in H II regions, often through oxygen abundance .
Stellar metallicity is the heavy-element abundance locked in stars. Integrated-light measurements are luminosity weighted unless a stellar-population reconstruction converts them to a mass-weighted quantity.
In a well-mixed closed-box model of galactic chemical evolution, gas consumed into locked stellar mass supplies a natural cumulative mass coordinate . The mean stellar metallicity is , giving the displayed derivative relation. If the birth abundance increases linearly, , its cumulative mean is half the current maximum. More generally the maximum of any nonnegative abundance distribution cannot lie below its mean. A fixed initial mass function and the same survival selection are required to identify this mass-weighted distribution with a star-count distribution.
The galaxy mass--metallicity relation is the empirical tendency for galaxies with greater galaxy stellar mass to have higher gas-phase metallicity and stellar metallicity. Mass-dependent metal loss, gas inflow, star-formation efficiency, and recycling all contribute.
The instantaneous recycling approximation treats short-lived stars as returning their ejecta immediately after formation while long-lived stars retain their mass indefinitely. It turns delayed chemical enrichment into local differential equations.
Under the instantaneous recycling approximation, forming mass locks into stars. If a fraction of returned material remains in the interstellar medium, the retained original metal mass is , and retained newly made metal mass is , where is the stellar yield per locked mass. Subtracting the metal mass initially consumed gives the displayed equation. Pristine galactic gas inflow adds gas but no metals; enriched inflow adds its metal mass separately. The retained fraction applies to both old and newly made metals in this idealization.
Let , let the interstellar medium have mass , and retain fraction of returned material. For put . The integrating factor for the metal mass is . A finite initial gas-phase metallicity removes the homogeneous solution and gives the displayed expression, equivalently for . The increasing initial gas mass requires pristine galactic gas inflow: gas accounting gives . A fixed initial mass function makes the birth metallicity distribution function proportional to when enrichment is monotone.
The stellar yield is the newly synthesized metal mass returned to gas per unit mass locked into long-lived stars, under a specified recycling convention and initial mass function.
The closed-box model evolves a fixed total baryonic mass with no inflow or outflow. Under instantaneous recycling and constant yield it predicts for gas fraction .
A finite-metal-fraction variant of the closed-box model of galactic chemical evolution uses effective stellar yield , rather than constant yield. With pristine initial gas and , metal accounting gives and hence . The mass-weighted mean stellar metallicity is . At final gas fraction , the metallicity distribution function is on . For trace abundances, and the usual closed-box metallicity distribution is recovered to leading order.
For a pristine closed-box model of galactic chemical evolution, and imply independently of the star formation rate. The resulting metallicity distribution function is exponential on . Its normalized density is . A fixed initial mass function and survival selection are needed to turn locked stellar mass into a stellar number distribution. Logarithmic abundance intervals have the additional factor .
With gross star formation rate , constant returned mass fraction , and the instantaneous recycling approximation, the net locked mass rate is . Mass conservation gives . For constant stellar yield per unit locked mass and initially pristine gas, metal conservation gives , so gas-phase metallicity grows as . Gross star formation and permanent locking have different normalizations.
The leaky-box model adds a galactic outflow to the closed box. If the outflow has the ambient gas metallicity and constant mass-loading factor , its effective yield is reduced to when returned fractions are absorbed into the definitions.
For initially pristine gas, zero bulk mass return, a constant stellar yield and a well-mixed galactic outflow of mass-loading factor , gas conservation gives and metal accounting gives . Consequently with . Since , complete depletion gives a normalized mass-weighted metallicity distribution function and mean stellar metallicity . A time-independent initial mass function makes the distribution of surviving tracers proportional to this distribution; a sample selected by light need not have the same weights.
The effective yield is the yield that a simple closed-box relation would need to reproduce an observed gas fraction and metallicity. Outflow and pristine inflow generally lower it below the nucleosynthetic yield.
The G-dwarf problem is the deficit of low-metallicity long-lived G dwarfs near the Sun relative to the prediction of a constant-yield closed-box model. Prolonged accretion of metal-poor gas is a standard ingredient in its resolution.
A metallicity distribution function gives the number or mass of stars per metallicity interval. Its interpretation depends on sample selection, stellar lifetimes, spatial migration, and whether metallicity means total heavy-element abundance or a particular abundance ratio.
Changing from linear stellar metallicity to its logarithm multiplies the metallicity distribution function by its Jacobian determinant. A flat distribution in linear metallicity rises exponentially in logarithmic metallicity. The commonly used iron abundance coordinate is equivalent to total-metallicity scaling only if relative element abundances are fixed.

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