Thermal energy versus electrostatic repulsion. The mean translational kinetic energy of one nonrelativistic thermal proton is
Using the center-to-center touching separation , the Coulomb barrier estimate is
Thus . Using rather than as the rough interaction distance doubles the estimate but leaves the conclusion unchanged. Typical solar thermal energies are far below the classical barrier. The two essential ideas are the high-energy tail of the thermal distribution and quantum tunnelling through the Coulomb barrier: neither a mean-energy estimate nor a sharp classical cutoff describes the reacting population.
For two equal-mass protons, let be their relative speed. In the center-of-mass frame each has speed , so their total collision energy is
Here is the reduced mass, not the stellar mean molecular weight.
In the low-energy, nonresonant approximation, the geometrical quantum-wave factor in a collision cross-section is proportional to the squared de Broglie wavelength, hence to . The slowly varying short-range reaction probability is absorbed into ; for proton–proton fusion it also includes the small weak-reaction probability. The rapidly varying exponential is the quantum tunnelling probability. For a Coulomb potential , its leading semiclassical exponent is
The integral follows from ; its dimensionless integral is . A finite nuclear radius modifies the short-distance factor absorbed into . In this convention : it is a penetration-energy scale, distinct from the classical contact energy .
Thermal averaging and pair counting. Each proton samples collision partners with number density and collision flux , so its collision rate is . Multiplying by the number of protons counts each identical pair twice. The thermonuclear reaction rate is therefore
The relative speed of two independent thermal protons has a Maxwell-Boltzmann velocity distribution with reduced mass . Changing variables with gives the normalized energy density
Substituting and the collision cross-section causes the energy powers to cancel:
The Gamow peak and its Gaussian width. Set . It diverges at either endpoint and has its unique minimum where
Thus the energy called in this question is the Gamow peak energy,
In the stellar tunnelling regime ,
This establishes the requested hierarchy in its physical regime; it is not an inequality valid at arbitrary temperature.
At the minimum, and . Hence
The Gaussian standard deviation is , small compared with when . Extending the lower endpoint to relative to the peak then gives
Combining this with the thermal prefactor yields the Gaussian approximation to a nonresonant thermonuclear rate,
At fixed reactant density and fixed , comparison with the requested temperature form gives
The constant here has dimensions of temperature; it is not inverse temperature. Resonances, plasma screening or variation of would require corrections to this particular approximation.