For a four-site cycle with site energy , three resonance integrals and one weakened integral , , put . In the independent-electron Hückel method, filling the two or four lowest spin orbitals gives total electronic energies and . At the square limit , these become and . The weakened-edge distortion raises the two-electron sum but lowers the four-electron sum. Near the latter change is , so its first-order term cancels. This electronic comparison omits structural repulsion and other restoring forces, and does not determine the open-shell spin at the square limit.
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