Interaction pressure tensor ($P_{ij}^{\varphi }$)

For a central differentiable pair potential, an exact local representation of the interaction momentum flux isHere $n_2$ is the two-particle number density. The line integral assigns each pair's exchanged momentum along the segment joining the particles. Translating both endpoints gives ${\partial }_s{n}_2=\mathbf{R}\cdot {\nabla }_{\mathbf{x}}{n}_2$. Integrating over $s$ and using pair-exchange symmetry proves that $-\nabla \cdot {\mathbf{P}}^{\varphi }$ is the interaction force density. Its homogeneous isotropic specialization gives the interaction part of the virial pressure from pair correlations. The kinetic pressure tensor accounts separately for random particle motion.