Victor Franz Hess's 1912 series used two sealed, 3-mm-walled ionization chambers with Theodor Wulf's fiber electrometers. Karl Bergwitz suggested internal plating; Günther & Tegetmeyer improved focusing. Basket-mounted ground comparisons, insulation-loss measurements, simultaneous detectors and barograph-derived heights supplied checks. The highest flight reached 5350 m; its comparisons came from Vienna and after landing, without a launch-site baseline.[ref]
A third, thin-walled chamber admitted ambient air. Hess multiplied its readings by , with pressure in millimeters of mercury, warning that vessel-wall contributions might violate this scaling. He recorded outside temperature but applied no absolute-temperature correction. Night flights, an eclipse and weather observations constrained alternatives to radiation from above; the eclipse argument addressed directly propagating solar radiation.[ref]
The electrometers read gradual electric potential loss caused by continuing air ionization. The low-altitude dip and strong high-altitude rise favored an extraterrestrial contribution, without measuring proton composition.[ref] An ionization chamber integrates electric charge: one energetic particle may create many ion pairs, several particles may contribute to one reading, and a photon can create charged particles in the gas or walls. A voltage-loss reading is therefore neither a count of primary cosmic rays nor a chemical analysis of them.
Domenico Pacini supplied independent evidence: in June 1911 he compared a copper-box-enclosed electroscope at the sea surface and 3 m underwater, more than 300 m offshore above an 8-m-deep seabed. Reduced underwater ionization, stable electrical loss between runs, and a lake comparison supported an external contribution independent of soil radioactive decay. Water provided shielding; this established a different constraint from Hess's altitude comparison.[ref]
Figure 1.
From air ionization to electrometer discharge
. Original functional schematic and invented readout example for the ionization-chamber charge-loss model. The chamber drawing is not a dimensional reconstruction, and the plotted voltage traces are not Hess's measurements. Details.
An elementary ionization-chamber charge-loss model makes the inference explicit. Let a positively charged electrode and its electrometer have effective capacitance , electric potential difference , and enclosed gas volume . Assume constant , a short enough interval that collection conditions remain stable, and no multiplication of charge in the gas. If ionization produces ion pairs per unit volume per unit time and a fraction is collected, then
Here is the elementary charge and is the parasitic electric current through imperfect insulation. Each fully collected ion pair transfers one elementary charge through the measuring circuit; counting its two opposite carriers as two transfers would introduce a factor-of-two error. The relation follows from charge conservation, rather than from a model of the incoming particle's identity.
For an invented example, take , , , a measured fall of , and a separately determined leakage-equivalent fall of . The leakage-subtracted fall is , so
This is about collected ion pairs per second throughout the chamber, not that many primary cosmic rays. Unknown collection losses make another uncertainty; changes in capacitance would require differentiating with both factors variable.
Gas density is a separate issue. Under a fixed radiation field, fixed gas composition and approximately constant energy deposited per unit gas mass, the volume-based ionization rate scales as . For a vented ionization chamber, the ideal gas law gives the illustrative correction
where is absolute temperature. A pressure-only correction presumes equal temperature. A sealed rigid chamber instead fixes gas number density as it rises: its internal pressure may change with temperature without losing gas. This does not make its insulation, electrometer calibration or collection efficiency insensitive to temperature. Nor can dividing by gas density correct arbitrary radiation from the vessel walls or changing particle energies. Those are distinct effects, not a universal normalization recipe.