To maximize a log-likelihood, use energy and Boltzmann distribution proportional to at temperature . Reversing this sign favors likelihood minima and can make the probability density function nonnormalizable. For Poisson observations with total and sample size , with respect to the normalized probability density function isIts mean is and variance , so it concentrates at the maximum-likelihood estimate as . Cooling of equilibrium laws and convergence of a particular changing-temperature chain are different statements; the latter requires mixing or a direct chain argument.
For independent binomial distribution observations with fixed trial count and total successes , the likelihood-power probability density function relative to is . Its normalized law is the displayed beta distribution. Its mean tends to and its variance tends to zero as , including endpoint maxima. Energy for maximizing a log-likelihood is its negative; the opposite sign reverses the optimization.
Let and . With Lebesgue base measure for , the likelihood-power law has conditionalsThe joint law is proper for , since its marginal is inverse-gamma distribution with shape and scale . There is also a direct convergence proof for successive Gibbs sampling updates with deterministic and . Update from , then from . Inverse-gamma distribution moments and conditional normal moments giveThe coefficients of the preceding moments are bounded by and , so these moments stay bounded from a finite deterministic initial variance. Letting gives and . Also . Thus the iterates converge in mean square to the normal maximum-likelihood estimate.
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