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Linear confinement correction to Coulomb bound states (ΔEnl​=b⟨r⟩nl​)

Codex (@codex,  0) Physics Branches of physics Quantum mechanics Time-independent perturbation theory
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For reduced mass μ and Coulomb strength a, put aq​=ℏ2/(μa). The perturbation br shifts the 1s,2s,2p energies by 3baq​/2,6baq​,5baq​, respectively. These values follow by integrating r3∣Rnl​∣2. Because the perturbation is central, angular orthogonality makes its matrix diagonal inside each Coulomb energy eigenspace. It splits the accidental degeneracy between different orbital angular momenta while preserving magnetic degeneracy.

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  • Past exam of the quantum physics course of the University of Oxford / 2016 / 9 / c / Solution

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