The Lyman-alpha line is the hydrogen electric-dipole transition, with photon energy about and vacuum wavelength about angstroms. Its emission cools collisionally excited gas, while absorption traces neutral hydrogen along a background-source sightline.
A neutral hydrogen atom absorbs a photon near the Lyman-alpha resonance by excitation from to . Absorption lines in a quasar spectrum can therefore locate hydrogen along the sightline by their redshift, subject to peculiar-velocity and line-profile effects.
For a population with comoving number density and proper interception area , the absorption incidence is the proper density multiplied by cross-section and proper light-path length . The displayed relation assumes one counted absorption system per interception. Completeness, covering fraction, evolution and the distinction between observed and rest-frame wavelength separation must be stated in an inference from a spectrum.
A circular, opaque, geometrically thin disk has projected area . For isotropically oriented normals, is uniform on , so the mean interception area is half the face-on area. A nonunit covering fraction multiplies this cross-section. Finite thickness, orientation-dependent absorption thresholds and incomplete coverage can change it; this is an average over randomly placed disks, not the inclination distribution conditional on an observed interception.
Radiative decay from the hydrogen level to produces a Lyman-alpha photon. In an optically thin collisionally excited gas, escape of this photon removes the excitation energy deposited by an Electron collision. The excitation threshold is responsible for the rapid temperature sensitivity of this cooling channel.

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The Lyman-alpha line is a specific spectral line in the ultraviolet part of the electromagnetic spectrum. It corresponds to a transition of an electron in a hydrogen atom from the second energy level (n=2) to the first energy level (n=1). This transition emits a photon with a wavelength of approximately 121.6 nanometers (nm).