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An axial charge is the spatial integral of the time component of an axial current. For a Dirac field and an internal generator $t$, it is $\int {\psi }^{†}{\gamma }_{5}t\psi d^{3}x$. Its canonical action rotates left- and right-handed fields oppositely. It is conserved only when the current divergence and flux at infinity vanish; Dirac masses and a chiral anomaly can obstruct conservation. The nonsinglet quark generators have no color anomaly and obey the nonsinglet axial charge algebra of quark densities.

For the Dirac equation with two equal quark masses $m$, the equations for $q$ and $\bar{q}$ give the divergence of the nonsinglet axial current as $im\bar{q}{\gamma }_5{\tau }_{a}q=m{P}_a$. The color chiral anomaly is absent in this nonsinglet identity because the quark flavor generator is traceless. Equivalently, the mass term in the Hamiltonian is $m\int S{d}^{3}x$, and the nonsinglet axial charge algebra of quark densities gives ${\dot{Q}}_{5,a}=m\int P_a{d}^{3}x$.

Let $t^A$ be Hermitian color generators with $\mathrm{Tr}(t^A{t}^B)={\delta }^{AB}/2$, and take $D_{\mu }={\partial }_{\mu }-i{g}_s{G}_{\mu }^A{t}^A$. In explicit spinor, color and flavor indices the massless kinetic term isThe full Quantum chromodynamics Lagrangian also has $-G_{\mu \nu }^A{G}^{A\mu \nu }/4$. A local color gauge transformation acts asThus $D_{\mu }q\mapsto V{D}_{\mu }q$ and the kinetic term is gauge-invariant.

Since the gauge coupling is independent of flavor and chirality, the classical internal global transformations are $q_L\mapsto U_L{q}_L$, $q_R\mapsto U_R{q}_R$, with constant flavor matrices $U_L,U_R\in U(2)$. Equivalently these consist of $SU(2{)}_L\times SU(2{)}_R$, a common vector phase, and a singlet axial phase $q\mapsto e^{i\eta {\gamma }_5}q$, modulo shared discrete factors. The vector phase measures quark number, or baryon number after dividing its generator by three. The nonsinglet axial rotations may be written $q\mapsto e^{-i{\theta }_a{\gamma }_5{\tau }_a/2}q$. At the quantum level the singlet axial phase is anomalous; the exact continuous internal symmetry is $SU(2{)}_L\times SU(2{)}_R\times U(1{)}_V$ up to those discrete identifications. The usual spacetime Poincaré transformations also leave the theory invariant; the massless classical theory has dilation symmetry, which is broken by quantum running. These distinctions are massless two-flavor QCD symmetries.

At equal time the canonical relations, including all indices, areNo constraint removes any of the four spinor components of the Dirac field in these equal-time relations.

To evaluate the axial charges, first prove the elementary bilinear identity. For any constant matrix $K$ on the spinor/flavor space,For example $[q_I^{†}{q}_J,q_K]=q_I^{†}\{q_J,q_K\}-\{q_I^{†},q_K\}{q}_J$; the spatial delta function collapses the integral. This proves the charge action directly from the canonical anticommutation relations.

For $K_a={\gamma }_5{\tau }_a/2$, anticommutation of ${\gamma }^0$ and ${\gamma }_5$ then givesThe charge is an even operator, so its commutator obeys the ordinary product rule. ConsequentlySimilarly, using ${\gamma }_5^2=1$ and the Pauli matrices identity $\{{\tau }_a,{\tau }_b\}=2{\delta }_{ab}I$,Composite fields can be defined with a common symmetry-preserving regulator; these nonsinglet identities have no color axial anomaly. This is the nonsinglet axial charge algebra of quark densities.

If every conserved axial charge left the vacuum invariant, the vacuum expectation of each such commutator would vanish. A nonzero quark chiral condensate instead makes $⟨[Q_{5,a},P_b]⟩=-i{\delta }_{ab}⟨S⟩\ne 0$ for $a=b$. It therefore diagnoses spontaneous breaking of the nonsinglet chiral symmetry. In the massless two-flavor limit, the observed hadronic pattern is described by $SU(2{)}_L\times SU(2{)}_R\to SU(2{)}_V$, with three Goldstone boson modes identified with the pions. The vacuum condensate is a dynamical property of QCD, not something derivable from the canonical algebra alone. The light pion multiplet and absence of parity-degenerate light hadrons support this pattern; the singlet axial anomaly prevents interpreting an additional singlet mode as a fourth Goldstone boson.

For equal nonzero masses, add ${\mathcal{L}}_m=-m\bar{q}q$. It is invariant under local color gauge transformations and common vector flavor rotations, but not under independent left/right rotations. The exact continuous flavor symmetry becomes $SU(2{)}_V\times U(1{)}_V$. The kinetic term and canonical anticommutators are unchanged, and the two proved equal-time commutators still hold. The charges, however, are no longer conserved:The first equation follows from the massive Dirac equations, or the last from $H_m=m\int S$ and $\dot{Q}=i[H,Q]$. This is the flavor-nonsinglet axial Ward identity with equal quark masses. The pions become pseudo-Goldstone bosons with $m_{\pi }^2=O(m)$, rather than exact massless modes. To leading order, in the convention $S=\bar{u}u+\bar{d}d$, $f_{\pi }^2{m}_{\pi }^2=-m⟨S⟩+O(m^2)$. The condensate persists for small masses, but the symmetry is now explicitly broken, so the exact-symmetry Goldstone argument is replaced by an approximate one. The singlet anomaly and gauge symmetry are unaffected.

A nonzero vacuum value of the scalar quark density breaks the massless nonsinglet chiral symmetry to its diagonal vector subgroup. Indeed, the nonsinglet axial charge algebra of quark densities gives $⟨[Q_{5,a},P_b]⟩=-i{\delta }_{ab}⟨\bar{q}q⟩$, whereas invariance of the vacuum under every conserved axial charge would make these expectations vanish. The three broken generators produce three massless Goldstone bosons in the exact chiral limit. Small equal quark masses explicitly break that symmetry and turn the pions into pseudo-Goldstone bosons, with squared masses linear in the quark mass at leading order.