Order-parameter stress

An advected order parameter contributes stress because a velocity gradient changes its free energy. For a polar vector this includes distortion, antisymmetric rotational, and symmetric flow-alignment stresses involving the molecular field.

Using the positive polar molecular field $h_i=\delta F/\delta p_i$ and velocity gradient ${\partial }_i{v}_j$, the reversible order-parameter stress consists of a distortion contribution and rotational and alignment contributions:For a local free-energy density, a representative is ${\Sigma }_{ij}^{(1)}=(f-p_k{h}_k){\delta }_{ij}-f_{{\partial }_i{p}_k}{\partial }_j{p}_k$. The Euler-Lagrange equation verifies its divergence. Integration by parts gives $\delta F=\int {\Sigma }_{ij}^p{\partial }_i{u}_j$ for an incompressible displacement without surface work; the corresponding mechanical power has the opposite sign. Pressure contributions may be reassigned in an incompressible flow.