Take the initial ground-state chemical atom at rest in the laboratory. The incident photon has energy and momentum . The excited chemical atom has rest mass and must carry that momentum. Conservation of energy and conservation of momentum give
Squaring cancels the photon-energy square:
Consequently
The extra positive term is the photon absorption recoil correction and supplies atomic recoil energy. The formula is exact for the initially stationary isolated chemical atom; it does not assume . Initial and final chemical atoms cannot both remain at rest during single-photon absorption without another body taking momentum.

Articles by others on the same topic (0)

There are currently no matching articles.