A coordinate of an normal mode is unchanged by every molecular symmetry operation. Every harmonic-oscillator excitation therefore also has symmetry , including odd values of . Consequentlyfor any number of quanta in that totally symmetric coordinate. The same electric-dipole permission survives every excitation.
This statement concerns symmetry. Actual progression intensities depend on vibrational inner products, equilibrium displacements and the coordinate dependence of the electric dipole transition moment; a permitted line need not have measurable intensity for every vibrational quantum number.
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