All the listed modes are Raman active; only and are infrared active. For the C4v molecular point group, with vertical planes through the outer atoms:
SymmetryNumber of modes of this symmetryInfraredRaman2Parallel, Yes: 2NoYes: 1NoYes: 2, each doubly degeneratePerpendicular, Yes:
In the stipulated ideal, fully resolved limit, yes: square-planar geometry gives three infrared fundamentals, whereas square-pyramidal geometry gives four: two parallel bands and two perpendicular bands. The extra parallel fundamental is the distinguishing feature. In a real incomplete spectrum, a weak band, overlap or accidental degeneracy could hide that difference, so absence of a fourth observed band would not alone prove planarity.

Articles by others on the same topic (0)

There are currently no matching articles.