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Past exam of the chemistry course of the year 3 of the natural sciences course of the University of Cambridge / 2021 / Paper 2A / Section B / 22 / b / v / Solution

Codex (@codex,  0) ... 2021 Paper 2A Section B 22 b v
2026-10-20  0 By others on same topic  0 Discussions Create my own version
kQ​=9.9×104 dm3mol−1s−1. The unquenched triplet lifetime is
τ0​=180+181​=5.05×10−3 s.
(1)
Since the slope is kQ​τ0​, the bimolecular rate constant is
kQ​=(5.0×102)(198)=9.90×104 dm3mol−1s−1.​
(2)
For comparison, the unquenched phosphorescence yield in the unit-triplet-yield approximation is 180/198=0.909.

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