Past exam of the frontiers of experimental condensed matter physics course of the University of Cambridge / 2013 / Paper 1 / 1 / c

In inelastic scattering, the probe transfers energy as well as momentum to the specimen. A neutron, X-ray or electron can create or annihilate a phonon, while electronic or magnetic excitations provide other channels. Measuring the incident and outgoing energies resolves the transfer $\hslash \omega$; their wavevectors determine momentum transfer $\hslash \mathbf{Q}$. In a crystal, phonon momentum is conserved modulo a reciprocal lattice vector. Resolved spectra therefore probe excitation dispersions and lifetimes, rather than only average atomic positions.

Thermal diffuse scattering arises from thermally populated lattice displacements and their correlations. The equilibrium lattice produces sharp Bragg peaks, but displacements redistribute part of the scattering into diffuse intensity. To one-phonon order a mode contribution contains a displacement projection and thermal occupation factors of the formwith atomic scattering weights, phases and geometrical factors understood. Stokes and anti-Stokes energy-resolved components carry $n_B+1$ and $n_B$ respectively; the displayed combination describes their summed scale. At high temperature, $n_B\simeq k_{B}T/(\hslash \omega )$, so soft modes and their polarization strongly influence the pattern. Zero-point motion also contributes at low temperature. An energy-integrating diffraction image can record this inelastic intensity as a diffuse background without resolving its small energy transfers. Static disorder gives additional diffuse scattering, so diffuse intensity alone does not establish a thermal mechanism.