With atomic displacement , the harmonic potential energy is . Newton's second law gives
For a periodic chain of atoms, its normal modes are , with and one representative per Brillouin zone. Substitution yields the monatomic-chain dispersion relation
A real general displacement is a superposition of these normal modes and their complex conjugates. The mode is a rigid translation. At small , the acoustic phonon branch is linear, with speed of sound
For , the group velocity is and vanishes at the zone boundary. The dashed initial tangent in the sketch has slope .
Figure 1.
Monatomic-chain dispersion and its sound-speed tangent
. Details.

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