Use the left -module structure on the tensor product of associative algebras. Expanding each in the basis shows that every tensor can be written
Thus the displayed family generates the module.
For uniqueness, let be the corresponding dual basis, with . Applying the linear map to a linear relation gives . Hence the family is linearly independent in a module, and
In particular is a basis of a module, with coefficients uniquely in .
Write uniquely as using part (i). For each , the equality becomes
The coefficient uniqueness from part (i) gives for every , so each belongs to the center of an associative algebra . Consequently .
Choose a basis of the vector space and rewrite . For , commuting with gives
Extend the linearly independent family to a basis of and apply its dual basis to the first factor. It follows that for every , hence . This proves .
Conversely, if and , then
The pure tensors span the tensor product, so is central, as is every sum of such pure tensors. Therefore the center of a tensor product of associative algebras is
These tensor products are identified with their natural vector subspaces of ; extending bases justifies these embeddings over the field .

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