A resonant Rabi pi pulse satisfies . The supplied therefore gives
The ideal rotating-frame operation is , a Pauli X gate up to global phase.
Both logical states belong to the electronic ground level. A fast electric dipole transition between them is forbidden, and spontaneous radiative relaxation at a hyperfine radiofrequency is weak. The optical readout field is off during the coherent pulse. Neglecting relaxation is therefore consistent with a population lifetime much longer than . Magnetic noise, collisions and technical dephasing are additional limitations; the ideal coherent calculation assumes their effects are small over this interval.
At detuning , define . The same two-level Hamiltonian operator gives
For an accurate fixed-duration rotation, the detuning must be small compared with the Rabi angular frequency. Writing ,
a fractional mismatch much smaller than relative to the carrier. This is an accuracy scale, not an assertion that a particular nonzero detuning gives a perfect gate.
The small-detuning error of a Rabi pi pulse quantifies a chosen tolerance. For an initial and the resonant pulse duration,
A population-transfer error at most consequently requires approximately ; for example, about for one percent error. Full gate calibration also includes pulse area and drive phase, beyond this population-transfer criterion.

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