A smooth vector field on a smooth manifold is a smooth section of a vector bundle of the tangent bundle projection , so . In a coordinate chart it has the form with smooth component functions .
Suppose a smooth vector bundle isomorphism covering the identity is given. For the standard basis of , put . These are smooth vector fields, and the linear isomorphism on each fibre makes a basis of .
Conversely, given such a global frame of a vector bundle, define
It is smooth, covers the identity and is a linear isomorphism on each fibre. Its inverse is smooth as well: in any coordinate chart, the component columns of the form an invertible smooth matrix , and the fibre coordinates of the inverse are . matrix inversion is smooth on the invertible matrices. Thus the tangent bundle is trivial exactly when a global frame exists, the defining property of a parallelizable manifold.
For a Lie group , write . A left-invariant vector field is a field satisfying
Such a field is determined by , since . Conversely, this formula defines a left-invariant field, by the chain rule and .
It also proves smoothness even if smoothness was not initially assumed. Choose a smooth curve with , . Then
Multiplication is a smooth map on a Lie group, so differentiating its coordinate functions in the second variable yields a smooth function of . This gives smooth components for in every local chart.
Choose a basis of , where , and left translate it. Each is a diffeomorphism, with inverse , so is a linear isomorphism and the translated fields are a basis at every . The explicit parallelization of a Lie group by left translations is
Its inverse sends to . Identifying with gives the required product bundle. The differential facts used are linearity, the chain rule, and smooth dependence of the differential of a smooth map on its base point.

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