Past exam of the mathematics course of the University of Cambridge / 2006 / iii / Paper 51 / 1 / a

An order parameter distinguishes phases by a macroscopic quantity that changes at the transition. For an Ising model ferromagnet it is the magnetization per Ising spin, $M=N^{-1}{\sum }_n⟨{\sigma }_n⟩$. At zero magnetic field the statistical Hamiltonian is invariant under spin inversion symmetry. The disordered phase preserves this symmetry, whereas a selected ordered phase has $M\ne 0$ and a spin-reversed partner with $-M$. At finite volume with symmetric boundary conditions the expected value is zero even below the transition; spontaneous magnetization means taking the thermodynamic limit before sending a symmetry-breaking field to zero.

Landau-Ginzburg theory introduces a coarse-grained local order parameter $\varphi (x)$ and a symmetry-constrained free-energy functional. For a short-range system with scalar spin inversion symmetry, a useful expansion isThe coefficients vary smoothly with microscopic control parameters at the level of the Landau approximation; normally $r=A(T-T_c)$ with $A>0$. The gradient term penalizes spatial variation. The magnetic field is conjugate to the order parameter, and odd powers at $h=0$ are excluded by spin inversion symmetry. With $u>0$, the sextic term may be omitted locally; with $u<0$, a stabilizing positive $v$ is essential. The equilibrium uniform order parameter minimizes the local potential $V(M)$, givingThis equation of state follows from minimization, rather than being imposed as an independent assumption. Vector or tensor order parameters and their allowed invariants describe other symmetry classes.