Take the vectors in the quantum state ensemble to be normalized, with and . The corresponding density matrix is
Each rank-one projector is a self-adjoint operator, so . For every in the Hilbert space,
proving that is positive semidefinite. The trace is .
Conversely, diagonalize a self-adjoint operator in an orthonormal eigenbasis, writing . Its positive semidefiniteness implies , and its unit trace gives . Thus is a quantum state ensemble with precisely this density matrix. Terms with zero eigenvalue may be omitted. This argument includes rank-one pure states; an ensemble representation need not describe a genuinely mixed state.
The stated condition is the definition of an extreme point in the convex set of density matrices. Suppose first that with , and consider any convex combination with all . For every orthogonal to ,
Every term is nonnegative, so for each . To see that this implies , expand , . The equality implies for every , which kills . Thus each density matrix vanishes on . By self-adjointness its range lies in the line , so . Its unit trace forces , establishing the required purity.
Conversely, suppose is not rank one. In its spectral decomposition, at least two eigenvalues are positive. Select a normalized eigenvector with positive eigenvalue ; then . Define
The remaining eigenvalues show that is a density matrix. The decomposition is a convex combination of two different density matrices, neither equal to . This violates the given purity condition. Hence the extreme points of the density-operator state space obey
Let and choose an orthonormal basis of . The reduced density matrix on is the partial trace
Here is the identity on , and the bras and kets in the sum contract only the second tensor factor. Equivalently, if , then . The definition is independent of the chosen basis: it is characterized by for every operator on .
The generalized measurement postulate takes to be operators on satisfying . The Born rule and the conditional state update give
If the outcome is not supplied to , the appropriate post-measurement density matrix is . For any local operator , cyclicity of the full trace gives
Since this holds for every , . This is the no-communication theorem.
The invariance concerns the nonselective measurement in quantum mechanics. A conditional reduced density matrix can change, although . For example, measuring one half of a Bell pair in the computational basis changes the other half conditionally to or ; before learning the outcome, its density matrix remains . Thus distant measurement in quantum measurements cannot transmit a controllable signal without classical communication. This quantum no-signalling is compatible with special relativity, even though some entangled states have correlations incompatible with a local hidden-variable theory.

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