Past exam of the mathematics course of the University of Cambridge / 2013 / iii / Paper 57 / 1 / b

The rotational invariance of a central-potential Hamiltonian allows a simultaneous eigenstate of energy and the two-dimensional orbital angular momentum $L_z=-i\hslash {\partial }_{\varphi }$. For a separated wavefunction $F(r)G(\varphi )$, the Laplacian in polar coordinates givesThe $\varphi$ term must be a constant; write $G^{\prime \prime }/G=-k^2$. The angular eigenfunctions can be chosen as $e^{ik\varphi }$. Single-valuedness under $\varphi \mapsto \varphi +2\pi$ imposes $e^{2\pi ik}=1$, hence $k\in \mathbb{Z}$. The radial equation in the separation of a two-dimensional central-potential eigenstate isFor a real central potential and the usual real self-adjoint radial boundary conditions, the radial equation admits a basis of real solutions: real and imaginary parts of a complex solution obey the same equation and boundary conditions. Choose a real normalized radial eigenfunction. Since the plane area element in plane polar coordinates is $rdrd\varphi$, the normalization isThis establishes the intended separated simultaneous eigenstate form. It is not the form of every stationary state. The radial equation depends on $k^2$, so the $k$ and $-k$ sectors have the same energy. For $k\ge 1$, their normalized superpositionis a single-valued stationary state with that energy but is not a single angular exponential. Quantum degeneracy is precisely why separation of variables selects a convenient eigenstate basis rather than all vectors in an energy eigenspace. The printed assertion needs this qualification. The printed polar-coordinate aid also labels a gradient component tuple as a divergence; the gradient used below is the two-dimensional vector $\hat{\mathbf{r}}{\partial }_r+\hat{\mathbf{\varphi }}{r}^{-1}{\partial }_{\varphi }$.

For the separated stationary state, restore its time factor $e^{-iEt/\hslash }$. Away from radial nodes, the quantum phase is $S=k\varphi -Et/\hslash$, up to a constant $0$ or $\pi$ where the real radial function has fixed sign. The guidance equation in plane polar coordinates therefore gives the Bohmian circulation of an angular-momentum eigenstateThe direction is $\hat{\mathbf{\varphi }}$ for $k>0$ and $-\hat{\mathbf{\varphi }}$ for $k<0$; the velocity is zero for $k=0$. Each admissible trajectory is a circle:The orbital angular momentum along the trajectory is $m{r}_0{v}_{\varphi }=\hslash k$. The origin or any zero-amplitude circle is excluded from this local formula. For the real degenerate superposition constructed above, the spatial quantum phase is constant on each nodal sector, so its Bohmian mechanics velocity is instead zero. Thus the circular motion is a conclusion about the separated angular-momentum eigenstate, not an arbitrary energy eigenstate.