Past exam of the mathematics course of the University of Cambridge / 2018 / iii / Paper 315 / 2 / a / iii

For uniform composition, the Schwarzschild criterion gives stability against convection whenA parcel displaced upward expands approximately adiabatically. If the ambient logarithmic temperature gradient is shallower than the adiabatic temperature gradient, the parcel cools more than its surroundings, becomes denser, and sinks back. Equality is neutral stability; a steeper gradient drives buoyant growth.

For a diatomic ideal gas with active translational and rotational degrees of freedom, $c_p/c_v=7/5$ and ${\nabla }_{\mathrm{ad}}=2/7$. If the infrared opacity is constant, $P\propto \tau$, so the profile's radiative temperature gradient isAn atmospheric thermal inversion has negative ${\nabla }_{\mathrm{rad}}$ and is stable by this criterion. Composition gradients require the Ledoux criterion; molecular dissociation and changing heat capacities can also change the numerical adiabatic temperature gradient.